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The synthesis of these planar pentadentate compounds was fairly straight-forward involving a ring expansion with alkynes or allenes with various substituents. The first product, resulting in phenyl substituents on the six-membered ring and the three-member ring was made with 3-ethynylthiophene and silver borohydride at room temperature. This product, as well as the ones with cyclohexane, cyclopropane, and thiophene substituents was characterized with NMR, high-resolution mass spectrometry, and elemental analysis, all of which confirmed a pentagonal bipyramidal structure and delocalized Os-C bonds. New CCCCC pentadentate chelates with properties for use in photothermal therapy
The Ethiopian birr crashed as the country neared its first coupon miss as the economy faces numerous internal and external shocks. In a statement on Friday, the government warned that it was not able to pay the coupon, worth about $33 million. Invezz — Ethiopian currency birr (USD/ETB) has tanked and it is not alone
Sodium bisulfite causes irritation to eyes, skin and mucous membranes if inhaled, ingested or comes in contact with eyes or skin, police officials said. ABC7 San Francisco — Eastbound Hwy 92 reopened in San Mateo after hazardous materials spill near Highway 101, authorities say - ABC7 San Francisco
Ms. Ma had been running a flower shop at Rua da Emenda for over 20 years, specializing in orchids, chrysanthemums, and narcissus. She told Xinhua that orchids were popular in Macao due to their long blooming period. "We start selling flowers for the Spring Festival in January, and it goes on for about a month." Feature: Macao welcomes Year of Dragon with blooming market-Xinhua
A member of the public discovered two malnourished Pitbull crossbreed pups abandoned at a bog in Donadea, County Kildare, and turned them over to the charity. Two Puppies Dumped in Bog Recovering Well - The Portugal News
A safety bollard was damaged and there were no injuries. Police allege man donned helmet while crashing his car into Geraldton Police Station's bollards - ABC News
Kim's Russia visit and show of bonhomie with President Vladimir Putin has heightened Western concerns that Moscow and Pyongyang may defy sanctions and engage in arms negotiations. WION — North Korean leader Kim Jong Un leaves Russia after underscoring bonhomie with Vladimir Putin - World News
Konrad said the most troubling finding in the study was the lack of either a trickle-down or a bottom-up effect linking lower and middle management to the top management teams. Report outlines how firms can effectively increase female representation
The project’s national researcher in Brazil and Director for Institutional Cooperation, International and Innovation in the Lula administration, Dr Dalila Andrade Oliviera, next reiterated the sentiments expressed by Heleno, emphasising that the learning circles project allows teachers and unions to shape learning and development from the bottom-up by working “with teachers in the classroom.” Education International — Working with teachers in classrooms to build bottom-up evaluation practices in Brazil
A delicious selection of breakfast foods including Eggs Benedict, Sweet Bread Pudding, Sausage or Ham Biscuits, and a Berry Delight Torte were served. The Stanly News & Press — Bless Your Spoon: Veterans breakfast - The Stanly News & Press | The Stanly News & Press
According to the researchers, if you divide the distance from the bregma to the inion by the distance from the nasal junction to the bregma, and then divide the size of the nasioniac arc by the bregma-inion distance, the two numbers form a ratio of roughly 1.6. ScienceAlert — The Golden Ratio Has Been Found in The Human Skull, But What Does It Mean? : ScienceAlert
For the new study, Tamargo and colleague Dr Jonathan A Pindrik, his co-author, examined the head CAT scans of 100 patients. Indeed, they found, the two sub-arcs on either side of the bregma are in a ratio that approximates the golden ratio. The Indian Express — The mysterious golden ratio: why is it everywhere, now in human skull? | Explained News - The Indian Express
Russian investigators are currently probing a case related to the biggest attempted bribe in recorded Russian history. FSB officers and officials from the Investigative Committee are said to have fabricated a murder case then tried to use it to extort 15 billion rubles ($200 million) from the alleged suspects, the owners of one of the country’s leading electronics trading companies. The brains behind the plot were the son of an old friend of Vladimir Putin and the business partner of Prime Minister Mikhail Mishustin’s son-in-law. The Bell — The plot to extort the biggest bribe in Russian history
The bureau said the actual amount incurred was around $170,000, and Chan used the money claimed to bribe Chiew. The Straits Times — Former AON S’pore CEO allegedly obtained $668k in bribes from Fullerton Healthcare Group ex-director | The Straits Times
“The ED investigation has revealed that M/s NKG Infrastructure Ltd obtained the bid by submitting forged/fake/false documents. Arora was aware of the fact that the company does not meet the technical eligibility and he received a bribe amount both in cash and in his bank accounts,” the spokesperson alleged. The Indian Express — ‘Ex-DJB chief engineer had passed on bribe money to AAP as election funds’: ED | Delhi News - The Indian Express
Deux patients atteins de bronchectasie ont vu leur état de santé s’améliorer grâce à une thérapie novatrice, selon les résultats d’une étude publiée dans la revue médicale American Journal of Respiratory and Critical Care Medicine. La plasmaphérèse, sorte de dialyse du sang a permis de nettoyer leur sang d’un anticorps responsable de leur infection chronique. Top Santé — Nettoyer le sang pour lutter contre les infections multi-résistantes - Top Santé
A 41-year-old man previously diagnosed with asthma presented with an influenza-like illness and breathlessness. He was treated for moderate-to-severe COVID-19 and exacerbation of asthma. CT pulmonary angiography (CTPA) revealed asymmetrical peribronchovascular ground-glass infiltrates consistent with COVID-19 and right main bronchial wall thickening with high-density material thought to be consistent with mucous impaction (figure 1A). He was discharged 8 days after admission. Thorax — Not all wheeze is asthma | Thorax
During the procedure, a doctor passes the bronchoscope into a person’s airways to help diagnose certain respiratory conditions and clear blockages. Flexible bronchoscopy: Uses, risks, preparation, what happens
In the Beatles Anthology book, Paul writes of going to Goodison with his Uncles, and mentions the bugler playing "Over the mountains, over the sea" when a shot went well over the bar. The Goodison Bugler’s Last Post – The Life of Francis Hamill
Then they applied the FastGC-PTR-MS to detect the isomers of butanol in latex paint, and found that the headspace of brand D latex paint mainly contained tert-butanol (4.41 ppmv), n-butanol, acetaldehyde, methanol, and acetone. The concentration of tert-butanol was much less than the maximum allowable concentration in the workplace (100 ppmv). EurekAlert! — Butanol in latex paint detected by FastGC-PTR | EurekAlert!